ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE
Zirconium Oxychloride Octahydrate
CAS: 13520-92-8
Molecular Formula: ZrOCl2·8H2O
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Names and Identifiers
| Name | Zirconium Oxychloride Octahydrate |
| Synonyms | Zirconyl chloride octahydrate dichlorooxozirconiumoctahydrate Zirconyl(IV) chloride octahydrate Zirconium Oxychloride Octahydrate Zirconium dichloride oxide hydrate dichloro(oxo)zirconium octahydrate ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE ZIRCONIUM(+4)CHLORIDE OXIDE OCTAHYDRATE oxozirconium dihydrochloride octahydrate |
| CAS | 13520-92-8 |
| EINECS | 231-717-9 |
| InChI | InChI=1/2ClH.8H2O.O.Zr/h2*1H;8*1H2;/q;+2/p-2/rCl2OZr.8H2O/c1-4(2)3;/h;8*1H2 |
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Physico-chemical Properties
| Molecular Formula | ZrOCl2·8H2O |
| Molar Mass | 322.25 |
| Density | 1.91 |
| Melting Point | 400°C (dec.) |
| Boling Point | 210°C |
| Water Solubility | SOLUBLE |
| Appearance | White crystal |
| Storage Condition | Room Temprature |
| Sensitive | Easily absorbing moisture |
| MDL | MFCD00149898 |
| Physical and Chemical Properties | colorless or white (sometimes yellowish) granular crystals without water of crystallization. Odorless, salty and cool. Density 2.49g/cm3. The melting point was 248-261 °c. Deliquescence. Soluble in water and alcohol. In high humidity air can absorb moisture deliquescence and become a solution. Heating to about 300 ° C began to release oxygen, high temperature is completely decomposed. With the acid release of oxygen and chlorine, and salts can also play a chemical role. There is a strong oxidation, and sulfur, phosphorus, carbon and other encounter will burn and explosion. Toxic! |
| Use | Used as grease additives, waterproofing agents and tanning agents |
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Risk and Safety
| Hazard Symbols | C - Corrosive |
| Risk Codes | R22 - Harmful if swallowed R34 - Causes burns |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | UN 3260 |
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Upstream Downstream Industry
| Raw Materials | Sulfuric acid Sodium hydroxide Hydrochloric acid |
| Downstream Products | Zirconium sulfate Zirconium Carbonate Zirconium(IV) oxide Zirconium 2-ethylhexanoate zirconium acetate zirconyl chloride |
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Introduction
The taste is astringent and hygroscopic. 6 molecules of crystal water are lost at 150 ℃ and anhydrous is formed at 210 ℃. Soluble in ethanol and ether, slightly soluble in hydrochloric acid, decomposed in water, insoluble in other organic solvents. Low toxicity, half lethal dose (rat, oral) 3500mg/kg. It's corrosive.
Last Update：2022-10-16 17:13:35
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Nature
| storage conditions | Store at 15°C to 25°C. |
| solubility | H2O: soluble |
| morphology | Crystalline Powder |
| Specific gravity | 1.91 |
| color | White to light yellow |
| Odor | Odorless |
| PH value | 1 (50g/l, H2O, 20℃) |
| water solubility | SOLUBLE |
| sensitivity | Hygroscopic |
| Merck | 14,10184 |
| stability | Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents. |
Last Update：2024-04-10 22:29:15
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Uses and synthesis methods
Toxicity
cough and exhalation after contact
symptoms such as rapid inhalation and conjunctival congestion. It should be operated under ventilation to prevent dust from spreading. Prevent suction and contact with eyes and skin. Wear safety articles at work, rinse your whole body after work, and rinse your eyes in large quantities when necessary. The maximum allowable concentration in the United States is 5 mg/m3.
chemical properties
white filamentous or needle-like crystals. Relative density 1.91. Melting point 400 ℃. 6 crystal water is lost at 150 ℃ and becomes anhydrous at 210 ℃. Soluble in water, methanol, ethanol and ether, slightly soluble in hydrochloric acid, insoluble in other organic solvents.
use
1. used as raw material for making zirconia. It is also used as rubber additive, coating desiccant, refractory, ceramic, glaze and fiber treatment agent.
2. intermediates of other zirconium products are also used as rubber additives, paint driers, etc.
3. Used as grease additive, waterproofing agent and tanning agent, etc.
4. Widely used in rubber additives, paint driers, refractory materials and ceramic glazes, etc.
production method
zirconium hydroxide hydrochloric acid method zircon and caustic soda melt, rinse, remove silicon and react with sulfuric acid, then add ammonia water to obtain zirconium hydroxide precipitate, dissolve the precipitate with hydrochloric acid to obtain zirconium oxychloride, which is evaporated and concentrated, cooled and crystallized, and crystallized to obtain zirconium oxychloride finished product. Its
ZrSiO3 4NaOH→Na2ZrO3 NazSiO3 2H2O
Na2ZrO3 3H2SO4→Zr(SO4)2 Na2SO4 3H2O
Zr(SO4)2 4NH3?H2O→Zr(OH)4↓ 2(NH4)2SO4
Zr(OH)4 2HCl 5H2O→ZrOCl2?8H2O
Last Update：2024-04-10 22:43:14
ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE - Security information
| WGK Germany | 1 |
| RTECS number | ZH7250000 |
| TSCA | Yes |
| customs code | 2827 49 90 |
| HazardClass | 8 |
| PackingGroup | III |
| Toxicity | LD50 orally in Rabbit: 3500 mg/kg |
Last Update：2024-04-10 22:29:15
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View History
Raw Materials for ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE
Downstream Products for ZIRCONIUM CHLORIDE OXIDE OCTAHYDRATE
Zirconium sulfate
Zirconium Carbonate
Zirconium(IV) oxide
Zirconium 2-ethylhexanoate
zirconium acetate
zirconyl chloride
Zirconium Carbonate
Zirconium(IV) oxide
Zirconium 2-ethylhexanoate
zirconium acetate
zirconyl chloride